The most common and most likely answer to this crossword clue is the 8 letter word REYNOLDS
I've seen this crossword clue in The Times
R
E
Y
N
O
L
D
S
More clues leading to the result REYNOLDS
Buddy explains!

The straight part
We know that "Painter" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case painter = reynolds.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.