The most common and most likely answer to this crossword clue is the 3 plus 2 plus 1 plus 4 letter word TWO OF A KIND
I've seen this crossword clue in The Daily Telegraph
T
W
O
O
F
A
K
I
N
D
Buddy explains!

The straight part
We know that "Pair" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case pair = two of a kind.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.