Cryptic crossword clue
Papal ambassador about to be accepted by new union 6

The most common and most likely answer to this crossword clue is the 6 letter word NUNCIO

I've seen this crossword clue in The Guardian
N
U
N
C
I
O


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What does NUNCIO mean?

NUNCIO noun
  1. The ecclesiastic title of a permanent diplomatic representative of the Roman Catholic Church to a sovereign state or international organization, who is accorded a rank equivalent to an accredited ambassador, and may also be given additional privileges including recognition as Dean in a country's diplomatic corps.
  2. (by extension) One who bears a message; a messenger.
  3. Any member of any Sejm of the Kingdom of Poland, Polish–Lithuanian Commonwealth, Galicia (of the Austrian Partition), Duchy of Warsaw, Congress Poland, or Grand Duchy of Posen.

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