The most common and most likely answer to this crossword clue is the 10 letter word CHESSPIECE
I've seen this crossword clue in Independent
C
H
E
S
S
P
I
E
C
E
Buddy explains!

The straight part
We know that "Perhaps rook" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case perhaps rook = chesspiece.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.