Cryptic crossword clue
Preppiest chain devised training scheme 14

The most common and most likely answer to this crossword clue is the 14 letter word APPRENTICESHIP

I've seen this crossword clue in The Daily Telegraph
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Buddy explains!

The straight part
We know that "training scheme" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case training scheme = apprenticeship.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does APPRENTICESHIP mean?

APPRENTICESHIP noun
  1. The condition of, or the time served by, an apprentice.
  2. The system by which a person learning a craft or trade is instructed by a master for a set time under set conditions.

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