Cryptic crossword clue
Proficient set excited teacher demanding the best? 13

The most common and most likely answer to this crossword clue is the 13 letter word PERFECTIONIST

I've seen this crossword clue in The Daily Telegraph
P
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Buddy explains!

The straight part
We know that "teacher demanding the best?" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case teacher demanding the best? = perfectionist.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does PERFECTIONIST mean?

PERFECTIONIST noun
  1. Someone who is unwilling to settle for anything that is not perfect or does not meet extremely high standards.
  2. Someone who thinks that religious or moral perfection can be attained in this life.
  3. One of the Bible Communists or Free-lovers, a small American sect founded by J. H. Noyes (1811-86), which settled at Oneida in 1848, holding that the gospel if accepted secures freedom from sin.
PERFECTIONIST adjective
  1. Demanding perfection; being a perfectionist; imposing overly high standards.
  2. Inclined or related to perfectionism.

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