The most common and most likely answer to this crossword clue is the 14 letter word PORT-AU-PRINCE
I've seen this crossword clue in Financial Times
P
O
R
T
-
A
U
-
P
R
I
N
C
E
Buddy explains!
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.