Cryptic crossword clue
Quack, quack! Duck walks in at the start 10

The most common and most likely answer to this crossword clue is the 10 letter word HOMEOPATHS

I've seen this crossword clue in The Guardian
H
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M
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Buddy explains!

The straight part
We know that "Quack, quack" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case quack, quack = homeopaths.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does HOMEOPATHS mean?

HOMEOPATHS noun
  1. A person who practices homeopathy.

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