Cryptic crossword clue
Quick-tempered, he’d catch out heartless chief 3-6

The most common and most likely answer to this crossword clue is the 10 letter word HOT-HEADED

H
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Buddy explains!

The straight part
We know that "Quick-tempered" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case quick-tempered = hot-headed.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

Crossword Answer definitions

HOT-HEADED adjective
  1. Pertaining to or characteristic of a hothead or hotheadedness; (of a person) easily excited or angered.

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