The most common and most likely answer to this crossword clue is the 8 plus 7 letter word NITROGEN DIOXIDE
I've seen this crossword clue in The Guardian
N
I
T
R
O
G
E
N
D
I
O
X
I
D
E
More clues leading to the result NITROGEN DIOXIDE
Buddy explains!

The straight part
We know that "poisonous gas" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case poisonous gas = nitrogen dioxide.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.