The most common and most likely answer to this crossword clue is the 10 letter word HIERARCHAL
I've seen this crossword clue in The Guardian
H
I
E
R
A
R
C
H
A
L
More clues leading to the result HIERARCHAL
Buddy explains!

The straight part
We know that "Relating to rank" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case relating to rank = hierarchal.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.