The most common and most likely answer to this crossword clue is the 7 letter word OLIVINE
I've seen this crossword clue in The Times
O
L
I
V
I
N
E
More clues leading to the result OLIVINE
Buddy explains!

The straight part
We know that "Rock" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case rock = olivine.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does OLIVINE mean?
OLIVINE noun- Any of a group of olive green magnesium-iron silicate minerals that crystallize in the orthorhombic system.