The most common and most likely answer to this crossword clue is the 14 letter word CLAUSTROPHOBIC
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More clues leading to the result CLAUSTROPHOBIC
Buddy explains!

The straight part
We know that "how must he feel in that chimney!" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case how must he feel in that chimney! = claustrophobic.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
Crossword Answer definitions
CLAUSTROPHOBIC noun- Someone with claustrophobia
- Suffering from claustrophobia; being scared of being enclosed in a confined space.
- Cramped and confined, so as to induce claustrophobia.