Cryptic crossword clue
School captain‘s striking effort, blocked by post … 10

The most common and most likely answer to this crossword clue is the 10 letter word HEADMASTER

I've seen this crossword clue in The Daily Telegraph
H
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Buddy explains!

The straight part
We know that "School captain" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case school captain = headmaster.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does HEADMASTER mean?

HEADMASTER noun
  1. A male school principal.

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