The most common and most likely answer to this crossword clue is the 5 plus 5 letter word SWEET TOOTH
S
W
E
E
T
T
O
O
T
H
More clues leading to the result SWEET TOOTH
Buddy explains!

The straight part
We know that "an addiction to cakes" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case an addiction to cakes = sweet tooth.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.