Cryptic crossword clue
Stress-free character seemingly calm, having walked away initially 5

The most common and most likely answer to this crossword clue is the 5 letter word SCHWA

I've seen this crossword clue in The Guardian
S
C
H
W
A


Buddy explains!

The straight part
We know that "Stress-free character" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case stress-free character = schwa.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does SCHWA mean?

SCHWA noun
  1. An indeterminate central vowel sound as the "a" in "about", represented as /ə/ in IPA.
  2. The character ə.

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