Cryptic crossword clue
Stuff thrown out in jamboree’s outside getting picked up by city volunteers 6

The most common and most likely answer to this crossword clue is the 6 letter word EJECTA

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Buddy explains!

The straight part
We know that "Stuff thrown out" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case stuff thrown out = ejecta.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does EJECTA mean?

EJECTA noun
  1. Material which has been ejected, especially from a volcano or an impact crater.

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