Cryptic crossword clue
Suppression of heartless monarch by church has popular backing at last

The most common and most likely answer to this crossword clue is the 9 letter word QUENCHING

I've seen this crossword clue in The Guardian
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Buddy explains!

The straight part
We know that "Suppression" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case suppression = quenching.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does QUENCHING mean?

QUENCHING verb
  1. To satisfy, especially an actual or figurative thirst.
  2. To extinguish or put out (as a fire or light).
  3. To cool rapidly by dipping into a bath of coolant, as a blacksmith quenching hot iron.
  4. To terminate or greatly diminish (a chemical reaction) by destroying or deforming the remaining reagents.
  5. To rapidly change the parameters of a physical system.
QUENCHING noun
  1. The extinction of any of several physical properties.
  2. The rapid cooling of a hot metal object, by placing it in a liquid, in order to harden it.

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