The most common and most likely answer to this crossword clue is the 13 letter word SEMIPERMEABLE
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Buddy explains!
The straight part
We know that "These kind of membranes I peel off when less new" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case these kind of membranes i peel off when less new = semipermeable.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does SEMIPERMEABLE mean?
SEMIPERMEABLE adjective- Permeable to some things and not to others, as a cell membrane which allows some molecules through but blocks other substances.