The most common and most likely answer to this crossword clue is the 10 letter word STARSTRUCK
I've seen this crossword clue in Financial Times
S
T
A
R
S
T
R
U
C
K
Buddy explains!
The straight part
We know that "Thrilled by celebrity" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case thrilled by celebrity = starstruck.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does STARSTRUCK mean?
STARSTRUCK adjective- Star-struck