Cryptic crossword clue
Thus little dictionary finally expressed “like bicarb, eg” 5

The most common and most likely answer to this crossword clue is the 5 letter word SODIC

S
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C

Buddy explains!

The straight part
We know that "like bicarb, eg" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case like bicarb, eg = sodic.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does SODIC mean?

SODIC adjective
  1. Of, relating to, or containing sodium.

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