Cryptic crossword clue
Time to visit Chilean cities after working out minor details 14

The most common and most likely answer to this crossword clue is the 14 letter word TECHNICALITIES

I've seen this crossword clue in Independent
T
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Buddy explains!

The straight part
We know that "minor details" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case minor details = technicalities.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does TECHNICALITIES mean?

TECHNICALITIES noun
  1. The quality or state of being technical.
  2. That which is technical, or peculiar to any trade, profession, sect, or the like.
  3. A seemingly insignificant detail with unexpected consequences

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