The most common and most likely answer to this crossword clue is the 3 letter word LOR
L
O
R
Buddy explains!

The straight part
We know that "That’s surprising!" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case that’s surprising! = lor.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.