Cryptic crossword clue
Unwitting detectives interrupt a copper facing gangster 10

The most common and most likely answer to this crossword clue is the 10 letter word ACCIDENTAL

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Buddy explains!

The straight part
We know that "Unwitting" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case unwitting = accidental.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does ACCIDENTAL mean?

ACCIDENTAL noun
  1. A property which is not essential; a nonessential; anything happening accidentally.
  2. Those fortuitous effects produced by luminous rays falling on certain objects so that some parts stand forth in abnormal brightness and other parts are cast into a deep shadow.
  3. A sharp, flat, or natural, occurring not at the commencement of a piece of music as the signature, but before a particular note.
  4. Part of a text that has a mainly structural purpose, such as spelling, punctuation or capitalization.
ACCIDENTAL adjective
  1. Not essential; incidental, secondary.
  2. Nonessential to something's inherent nature (especially in Aristotelian thought).
  3. Adjusted by one or two semitones, in temporary departure from the key signature.
  4. Occurring sometimes, by chance; occasional.
  5. Happening by chance, or unexpectedly; taking place not according to the usual course of things; by accident, unintentional.
  6. Being a double point with two distinct tangent planes in 4-dimensional projective space.

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