Cryptic crossword clue
Very tiny boat with a man in charge 9

The most common and most likely answer to this crossword clue is the 9 letter word SUBATOMIC

I've seen this crossword clue in The Guardian
S
U
B
A
T
O
M
I
C


Buddy explains!

The straight part
We know that "Very tiny" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case very tiny = subatomic.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does SUBATOMIC mean?

SUBATOMIC adjective
  1. Relating to particles that are constituents of the atom, or are smaller than an atom; such as proton, neutron, electron, etc.
  2. Relating to any length or mass that is smaller in scale than a the diameter of a hydrogen atom.

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