Cryptic crossword clue
Volunteers to go after one old Greek character 4

The most common and most likely answer to this crossword clue is the 4 letter word IOTA

I
O
T
A


Buddy explains!

The straight part
We know that "Greek character" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case greek character = iota.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does IOTA mean?

IOTA noun
  1. The ninth letter of the Greek alphabet.
  2. A jot; a very small, insignificant quantity.

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