Cryptic crossword clue
Bloomer by Labour leader once, having upset 625% of Scotland first 9

The most common and most likely answer to this crossword clue is the 9 letter word COLTSFOOT

I've seen this crossword clue in The Guardian
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Buddy explains!

The straight part
We know that "Bloomer" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case bloomer = coltsfoot.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does COLTSFOOT mean?

COLTSFOOT noun
  1. An herbaceous plant, species Tussilago farfara, that grows in Europe and the Middle East.
  2. Various flowering plants in the genus Petasites native to Europe or Asia.
  3. Homogyne alpina (alpine coltsfoot or purple colt's-foot).

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