Cryptic crossword clue
Expressionless seeing something red hot, tipped over coffee 5-5

The most common and most likely answer to this crossword clue is the 11 letter word POKER-FACED

I've seen this crossword clue in The Guardian
P
O
K
E
R
-
F
A
C
E
D

Buddy explains!

The straight part
We know that "Expressionless" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case expressionless = poker-faced.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

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